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71.
72.
On the interpretation of peak metamorphic temperatures in light of garnet diffusion during cooling 总被引:13,自引:0,他引:13
F. S. SPEAR 《Journal of Metamorphic Geology》1991,9(4):379-388
Abstract Finite difference models of Fe-Mg diffusion in garnet undergoing cooling from metamorphic peak conditions are used to infer the significance of temperatures calculated using garnet-biotite Fe-Mg exchange thermometry. For rocks cooled from high grades where the garnet was initially homogeneous, the calculated temperature (Tcalc) using garnet core and matrix biotite depends on the size of the garnet, the ratio of garnet to biotite in the rock (Vgarnet/Vbiotite) and the cooling rate. For garnets with radii of 1 mm and Vgarnet/Vbiotite<1, Tcalc is 633, 700 and 777°C for cooling rates of 1, 10 and 100°C/Ma. For Vgarnet/Vbiotite= 1 and 4 and a cooling rate of 10° C/Ma, Tcalc is approximately 660 and 610° C, respectively. Smaller and larger garnets have lower and higher Tcalc, respectively. These results suggest that peak metamorphic temperatures may be reliably attained from rocks crystallized at conditions below Tcalc of the garnet core, provided that Vgarnet/Vbiotite is sufficiently small (<0.1) and that the composition of the biotite at the metamorphic peak has not been altered during cooling. Numerical experiments on amphibolite facies garnets with nominal peak temperatures of 550–600° C generate a ‘well’in Fe/(Fe + Mg) near the rim during cooling. Maximum calculated temperatures for the assemblage garnet + chlorite + biotite + muscovite + plagioclase + quartz using the Fe/(Fe + Mg) at the bottom of the ‘well’with matrix biotite range from 23–43° C to 5–12° C below the peak metamorphic temperature for cooling rates of 1 and 100° C/Ma, respectively. Maximum calculated temperatures for the assemblage garnet + staurolite + biotite + muscovite + plagioclase + quartz are approximately 70° C below the peak metamorphic temperature and are not strongly dependent on cooling rate. The results of this study indicate that it may be very difficult to calculate peak metamorphic temperatures using garnet-biotite Fe-Mg exchange thermometry on amphibolite facies rocks (Tmax > 550° C) because the rim composition of the garnet, which is required to calculate the peak temperature, is that most easily destroyed by diffusion. 相似文献
73.
The steepest descent(or ascent)search is employed for finding optimum diffusion coefficients in T42L9Gmodel,with a view to improving the model's computational stability or prediction accuracy.The method of thesteepest descent search is first described,in which the golden section search is chosen as the fundamental one-dimensional search used in the multi-dimentional steepest descent search,and then the optimization of the dif-fusion coefficients is described. 相似文献
74.
Evaluation and application of dialysis porewater samplers for microbiological studies at sediment-water interfaces 总被引:1,自引:1,他引:1
The equilibrium diffusion technique has become a valuable tool for ecological and biogeochemical studies in aquatic environments. In sediment ecosystems, changes in concentration of microbial metabolites with increasing depth can be determined dependably and reproducibly with this technique. Since the permeation characteristics of the membranes employed are crucial, selecting the proper membrane requires knowledge about its behavior under conditions which prevail in the natural environment. Thirteen polymer sheets were evaluated comparing permeation terms for biogeochemically relevant solutes, biodegradability, and mechanical strength. Cellulose-based dialysis membranes are most satisfactory when employed in low temperature anoxic environments. For this membrane, correction terms were calculated to account for diffusion losses during retrieval and sampling. Optimal incubation times can now be predicted from experimentally determined permeation coefficients for several porewater solutes. Dialysis porewater samplers (DPS) have been successfully applied during more than 100 independent experiments for the collection of interstitial water from surface sediments. DPS were used for water depths as deep as 290 meters. 相似文献
75.
We have theoretically considered the problem of interpretation of nutrient profiles in the upper ocean (100–2000m). We compare
the experimental depth profiles of nonconservative tracers, both stable and radioactive, with solutions of one-dimensional
steady state transport equations of increasing complexity including situations not encountered in the real oceans. Apart from
gaining insight into the nutrient transport processes, this analysis is useful in offering a way to obtain operational estimates
of depth dependent/independent eddy diffusivity and dissolution fluxes in the ocean. These parameters are essential for estimating
new production, total production and burial of carbon in the sediments. 相似文献
76.
A new experimental method is introduced for determining the relative magnitudes of liquid and vapor diffusion by using a small amount of soluble chemical as a tracer. The theoretical justification of the method is presented for the case where ice is absent. The feasibility of the method is demonstrated by an experiment using marine-deposited clay. 相似文献
77.
Tang Yuanjun 《地球科学》1986,(1)
以江西德兴斑岩铜矿床之细矿脉为研究对象,文章介绍了细矿脉剖面采集及研究的工作方法,着重讨论了自矿脉至围岩元素的空间展布特征。成矿元素Cu、Ag、S和控矿元素Fe、Rb、K都属确定性分布型。对照元素的扩散和渗滤理想模式,得到如下认识:在成矿成晕的地球化学过程中,成矿元素Cu、Ag、S以及Fe以扩散作用为主,控矿元素K和Rb以渗滤作用为主。 相似文献
78.
对流边界层(CBL)中的污染扩散是非高斯型的。本文在下列三个假设下建立了双高斯型几率分布函数(PDF)模式:1.对流边界层任一确定高度铅直速度W的几率分布函数pw由两个高斯分布迭加而成;2.从污染源释放的粒子具有源高的铅直速度几率分布,且其轨迹是线性的;3.粒子在地面的反射为全反射,在混合层高度Zi为全反射或有部分吸收。然后分析了三个高度上铅直速度W的一些统计特征量,比较了由PDF模式计算的横风向积分浓度和Lamb的数值模拟[1-3],Deardorff的水槽模拟[4-6]结果,并用美国CONDORS计划的外场试验资料[7]对PDF模式进行了验证,结果均相当一致。 相似文献
79.
闾阳-海城-东沟剖面深地震波动力学特征初探 总被引:1,自引:0,他引:1
本文利用国内外有关深地震波动力学特征的研究方法,结合现有原始资料的实际条件,对闾阳-海城-东沟深地震测深剖面某些地段的主要波组的动力学特征进行了定性或半定量的分析与研究。在频谱分析,速度振幅的计算与相对理论振幅的对比等方面,获得了一些有益信息。为进一步合理解释深地震测深资料提供依据。 相似文献
80.
Further Studies Of Atmospheric Turbulence In Layers Near The Surface: Scaling The Tke Budget Above The Roughness Sublayer 总被引:2,自引:0,他引:2
The second of two experimental studies of the TKE budget conducted on sites of different roughness is described, and results are compared. The first took place within a shallow layer above a small field of mostly bare, cultivated soil; the second was carried out above a roughness sublayer of significant depth on an extensive plain of tall dry grass. Budget terms observed in the second study were scaled with a modified u which compensated for effects of an unusually large stress gradient and ensured that the m functions would be collinear. By showing that the modification becomes negligible in smaller gradients, it is demonstrated that in normal conditions, budgets observed above significant roughness sublayers should be normalized by scaling in terms of the unreduced Reynolds stress at the sublayer's upper surface. This procedure is shown to be consistent with the expectation that TKE budgets in layers near the surface all scale in fundamentally the same way.Other findings include: (1) the fact that most m functions previously reported are not quite collinear is attributed to a type of overspeeding known to affect three-cup anemometers; (2) revised m functions, collinear and largely free of the effects of overspeeding, are determined from a well-established characteristic of the linear m relation for the stable case; (3) data that define collinear m functions can also be represented with single hyperbolic curves; (4) dissipation is found to be 10 to 15% too small to balance total TKE production in unstable and neutral conditions and to decrease with increasing z/L in thestable regime; and (5) new relations for based on the observed behaviour of the dissipation deficit provide an improved closure for the set of equations that express the budget terms as functions of m and z/L. 相似文献